Reactions of O22+ with CO2, OCS and CS2
نویسندگان
چکیده
منابع مشابه
IR photodissociation spectroscopy of (OCS)n(+) and (OCS)n(-) cluster ions: Similarity and dissimilarity in the structure of CO2, OCS, and CS2 cluster ions.
Infrared photodissociation (IRPD) spectra of (OCS)n(+) and (OCS)n(-) (n = 2-6) cluster ions are measured in the 1000-2300 cm(-1) region; these clusters show strong CO stretching vibrations in this region. For (OCS)2 +) and (OCS)2(-), we utilize the messenger technique by attaching an Ar atom to measure their IR spectra. The IRPD spectrum of (OCS)2 (+)Ar shows two bands at 2095 and 2120 cm(-1). ...
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The rotational spectra of nine isotopes of the mixed trimer, OCS–~CO2!2, have been assigned using pulsed nozzle FTMW spectroscopy techniques. The structure resembles a distorted triangular cylinder. It can be thought of as the slipped (CO2)2 dimer with the OCS above the dimer and crossed about 23° to the axis of each CO2. The distance between the carbon atoms on the CO2 is 3.68~5! Å. The distan...
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ژورنال
عنوان ژورنال: International Journal of Mass Spectrometry
سال: 2013
ISSN: 1387-3806
DOI: 10.1016/j.ijms.2013.06.018